Every comp has a side-chain. The side-chain is the control circuitry that uses the audio signal to generate a control signal for compression. If the side-chain uses the audio signal before the "comp" circuitry it is called feed forward, if the side-chain uses the audio signal after the "comp" circuitry it is then called feed back.
Any audio signal that bleeds thru on the side-chain control voltage will cause a multiplier distortion effect on the compressed audio signal (this happens in every type of compressor). This distortion is harmonically 'in-tune' with the input audio, so it mostly sounds pleasing. Optical, just by their nature, filters some of the higher frequency audio bleed thru that may be present on the side-chain control voltage and the result is small harmonic audio distortions in low and mid frequencies.
One of the biggest contributors to these comps that have this distortions/character, is the old electrolytic caps that are still in place in these older units side-chains. Even when these caps were new, their ESR (equivalent series resistance) values kinda sucked compared to what we have today. So, even back in the 60's and 70's, new units would have more of these distortions than a vintage unit that has been re-capped with modern electro caps of today. There are ways to re-cap and preserve that vintage tonal magic, but the technician would have to be aware and know what to do.
-Frank